Sunrise is one of the most magical hours on Santorini. “There is no better start to the day than with morning yoga on the roof of a cave suite at Mystique, overlooking a volcano that wakes up together with you,” Kalia shares. The volcano, called Nea Kameni, is still active (the last major activity was in 1950), has played an essential role in the formation of the ancient island.

Traditional Greek breakfast is equal parts healthful and hardy, and the spread at Mystique does not disappoint. Kalia notes that “breakfast at the hotel is by far a must-do as the menu is highly selective and highly nutritional, including both traditional and vegan options.” Menu standouts include Greek yogurt with berries, gluten-free pancakes with local honey, and eggs with a mix of herbs and feta. Dine on your suite’s open balcony, or at the hotel’s Opens in a new windowCharisma restaurant.

To begin the day in earnest, set out to explore Megalohori, an unspoiled, traditional village where the pace of life has changed very little throughout the years. Nestled at the heart of the village lies Vedema, Kalia’s other property. “Megalohori is a carefree place where children can play in the streets and every neighbor is a friend,” says Kalia. After wandering the picturesque lanes lined with charming white stucco houses and shops, make your way over to Perivolos Beach, famous for its striking black volcanic sand and pleasant waves.

After enjoying the sand and surf, Opens in a new windowMr. E is the destination for a sublime lunchtime experience. The restaurant is set right on the beach and is led by Noma alum Alexandros Tsiotinis, who serves contemporary Mediterranean fare in an airy, artful environment just steps from the water’s edge. Mr. E is a character, a metaphor for the worldly and epicurean nature of so many of the island’s residents and visitors. “He embodies the culture of the island as a concept. He connects with Santorinian cuisine and pays tribute to family recipes and local produce, anchoring the past to the present,” Kalia notes.

Some of her favorites on the menu are the Santorinian Salad with caper leaves, cherry tomatoes, cucumber, oregano pesto, carob rusk, and chloro cheese. Or, try the Santorinian Fava Tart, with poached egg, sausage, chutney, and Greek Truffle. The Grilled Octopus, simply prepared with olive oil and spices, is an eternal favorite.

After an active afternoon, a drink is certainly in order. Stop by Mystique’s Opens in a new windowAura Bar for a glass of famous Santorini Assyrtiko wine while you enjoy a breathtaking vista out over the Aegean.